ISO 15632:2021 pdf download - Microbeam analysis

ISO 15632:2021 pdf download.Microbeam analysis — Selected instrumental performance parameters for the specification and checking of energy-dispersive X-ray spectrometers (EDS) for use with a scanning electron microscope (SEM) or an electron probe microanalyser (EPMA).

ISO 15632 defines the most important quantities that characterize an energy-dispersive X‑ray spectrometer consisting of a semiconductor detector, a pre-amplifier and a signal-processing unit as the essential parts.

ISO 15632 is only applicable to spectrometers with semiconductor detectors operating on the principle of solid-state ionization.
ISO 15632 specifies minimum requirements and how relevant instrumental performance parameters are to be checked for such spectrometers attached to a scanning electron microscope (SEM) or an electron probe microanalyser (EPMA).

Progress in energy-dispersive X-ray spectrometry (EDS)by means of improved manufacturingtechnologies for detector crystals and the application of advanced pulse-processing techniques haveincreased the general performance of spectrometers,in particular at high count rates and at lowenergies(below 1 kev)。Meanwhile,the Si-Li detector technology has been successfully replaced by thesilicon drift detector (SDD)technology which provides performance comparable to Si-Li detectors,evenat considerably higher count rates.In addition,a smaller detector capacitance results in the capabilityof measuring even higher count rates and in the availability of larger area detectors.This documenthas therefore been updated with criteria for the evaluation of the performance of such modernspectrometers.
A spectrometer is commonly specified by its energy resolution at high energies defined as the fullpeak width at half maximum (FWHM)of the manganese Ka line.To specify the properties in thelow energy range,values for the FWHM of carbon K,fluorine K or/and the zero peak are given by themanufacturers.Some manufacturers also specify a peak-to-background ratio,which may be defined asa peak-to-shelf ratio in a spectrum from an 55Fe source or as a peak-to-valley ratio in a boron spectrum.Differing definitions of the same quantity have sometimes been employed.The sensitivity of thespectrometer at low energies related to that at high energies depends strongly on the construction ofthe detector crystal and the X-ray entrance window used.Although high sensitivity at low energies isimportant for the application of the spectrometer in the analysis of light-element compounds,normally,the manufacturers do not specify an energy dependence for spectrometer efficiency.
This document was developed in response to a worldwide demand for minimum specifications ofan energy-dispersive X-ray spectrometer.EDS is one of the most applied methods used to analysethe chemical composition of solids and thin films.This document should permit comparison of theperformance of different spectrometer designs on the basis of a uniform specification and help tofind the optimum spectrometer for a particular task.In addition,this document contributes to theequalization of performances in separate test laboratories.In accordance with ISO/IEC 1702501,suchlaboratories should periodically check the calibration status of their equipment according to a definedprocedure.This document may serve as a guide for similar procedures in all relevant test laboratories.